Carbonaceous Nanostructured Support Materials for Low Temperature Fuel Cell Electrocatalysts—A Review

• 作者: Maryam Yaldagard Mohsen Jahanshahi Naser Seghatoleslami
• 来源期刊: 纳米科学与工程(英文)
• 学科: 化学
• 关键词: Low Temperature Fuel Cell PEMFC DMFC Pt-Based ELECTROCATALYST Nanostructured-Supports Durability/Stability
• 年，卷（期）: nmkxygcyw_2013,（4）
• 页码范围: 121-153
• 页数: 33页
• 分类号: O6

摘要

Highly-dispersed platinum and platinum-based catalysts on a conductive support are commonly used as electrode materials in low-temperature fuel cells, particularly the hydrogen PEMFC and the direct methanol PEMFC. The performance and durability/stability of these catalysts strongly depend on the characteristics of the support. Catalysts supported on high surface area carbon black are widely used in low-temperature fuel cells. However, the corrosion of carbon black has been recognized as one of major causes of performance degradation and durability issues of low-temperature fuel cells under high-potential conditions. So the need for alternative supports with outstanding physical and mechanical properties to carry out the successful reaction in catalyst layer and give a longer lifetime for the electrocatalysts is inevitable. The emergence of nanotechnology and development of nanostructure materials in recent years has opened up new avenues of materials development for low-temperature fuel cells. This paper presents the performance with a variety of carbon-based nanostructured materials such as carbon nanotubes (CNT), carbon nanofibers (CNF), carbon aerogels, nanoplates of graphene, etc. So the present paper provides an overview of these nanostructured materials as low-temperature fuel cell catalyst supports. The improved characteristics of the nanostructured supports with respect to commercially used carbon black (Vulcan XC-72) and their effect on the electrochemical activity are highlighted. Additionally, it reviews the literature on the synthesis of nanostructured-supported Pt electrocatalysts for proton exchange membrane (PEM) fuel cell catalyst loading reducing through the improvement of catalyst utilization and activity. The features of each synthetic method were also discussed based on the morphology of the synthesized catalysts.