The Catalytic Copolymerization of Ethene with Carbon Monoxide Efficiently Carried out in Water-Dichloromethane-Sodium Dodecylsulfate Emulsion

• 作者: Andrea Vavasori Claudio Tortato Giuseppe Quartarone Lucio Ronchin
• 来源期刊: 催化剂现代研究(英文)
• 学科: 化学
• 关键词: Palladium Catalyst CARBONYLATION COPOLYMERIZATION POLYKETONE
• 年，卷（期）: 2013,（3）
• 页码范围: 93-99
• 页数: 7页
• 分类号: O6

摘要

The CO-ethene copolymerization has been efficiently carried out in the water/CH2Cl2 emulsion by using water insolvable Pd(II) complexes. By using the surfactant SDS very high molecular weight copolymers have been obtained with high productivity (ca. 13,000 g/(gPd.h)).