Crystallization Kinetics of Melt-Blended Low-Density Phthalic Anhydride with a Low-Tg Tin-Phosphate

• 作者: Laila M. Al-Harbi
• 来源期刊: 高分子化学期刊(英文)
• 学科: 化学
• 关键词: Polyamides CRYSTALLINITY Phosphate Glass-Polymer HYBRIDS DSC and Kinetics
• 年，卷（期）: 2014,（3）
• 页码范围: 38-46
• 页数: 9页
• 分类号: O6

摘要

Polyamide prepared by the reaction of ethylene diamine with different ratios between 1,6-glyconic acid and phthalic anhydride. The differential scanning calorimetry (DSC) is used to study the nonisothermal and isothermal crystallization of low density polyamides in phosphate glass (Pglass)-polymer hybrid blends. The % crystallinity decreased as the Pglass volume increased. The half-life (t1/2) for crystallization decreased as the propagation rate constant rose for both the polymer matrices with increasing Pglass concentrations. The results show that the Pglass is improved nucleating agent for formation of the Pglass-polymer hybrids up to 35% Pglass and the energy necessary to break decreased. The stability of the reaction of ethylene diamine with phthalic anhydride and glyconic acid was qualitatively investigated using molecular orbital calculations.