Generalized Electron Balance for Dynamic Redox Systems in Mixed-Solvent Media

• 作者: Anna Maria Micha?owska-Kaczmarczyk Tadeusz Micha?owski
• 来源期刊: 分析科学方法和仪器期刊(英文)
• 学科: 化学
• 关键词: Electrolytic Redox Systems GENERALIZED ELECTRON BALANCE MIXED-SOLVENT MEDIA
• 年，卷（期）: 2014,（4）
• 页码范围: 102-109
• 页数: 8页
• 分类号: O6

摘要

A complex example of electrolytic redox system involving 47 species, 3 electron-active elements and five (3 am-phiprotic + 2 aprotic) co-solvents, is presented. Mixed solvates of the species thus formed are admitted in the system considered. It is proved that the Generalized Electron Balance (GEB) in its simplest form obtained according to the Approach II to GEB is identical with the one obtained for aqueous media and binary-solvent system, and is equivalent to the Approach I to GEB.