In this paper, we introduce and study GC-flat complexes over a commutative Noetherian ring, where C is a semidualizing module. We prove that Ge-flat complexes are actually the complexes of Go-flat modules. This complements a result of Yang and Liang. As an application, we get that every complex has a GF-C(C)-cover, where GFC(C) is the class of Ge-flat complexes. We also give a characterization of complexes of modules in HC(FC) that are defined by Sather-Wagstaff, Sharif and White.