In order to know the current collaborative development situation and relationship of E-commerce and logistics, the paper evaluates the whole collaborative development level of Chinese E-commerce and logistics from 2008 to 2014 using the DEA model. Fund, infrastructure, labor and collaborative development are evaluated and analyzed in this model. The research indicates that E-commerce facilitates the logistics development but logistics can’t support E-commerce development well due to the lag effect which leads to lower collaborative development level. So optimizing the ratio of logistics investment and output, promoting logistics service quality and accelerating logistics development have been the key factors for promoting the collaborative development of E-commerce and logistics.