NixWO2.72 nanorods as an efficient electrocatalyst for oxygen evolution reaction

• 作者: Adriana Mendoza-Garcia Daniel P.Erdosy Dong Su Huiyuan Zhu Junrui Li MiaoFang Chi Shouheng Sun Zheng Xi
• 来源期刊: 绿色能源与环境：英文版
• 学科: 化学
• 年，卷（期）: 2017,（2）
• 页码范围: 119-123
• 页数: 5页
• 分类号: O643.36

摘要

NixWO2.72 nanorods（NRs） are synthesized by a one-pot reaction of Ni（acac）2 and WCl4. In the rod structure, Ni（Ⅱ） intercalates in the defective perovskite-type WO2.72 and is stabilized. The NixWO2.72 NRs show the x-dependent electrocatalysis for the oxygen evolution reaction（OER） in 0.1 M KOH with Ni0.78WO2.72 being the most efficient, even outperforming the commercial Ir-catalyst. The synthesis is not limited to NixWO2.72 but can be extended to MxWO2.72（M = Co, Fe） as well,providing a new class of oxide-based catalysts for efficient OER and other energy conversion reactions.