Effect of Niobium on Microstructure and Properties of the CoCrFeNbxNi High Entropy Alloys
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摘要:
A series of CoCrFeNbxNi (x values in molar ratio,x =0,0.25,0.45,0.5,0.75,1.0 and 1.2) high entropy alloys (HEAs) was prepared to investigate the alloying effect of Nb on the microstructures and mechanical properties.The results indicate that the prepared CoCrFeNbxNi (x > 0) HEAs consist of a simple FCC solid solution phase and a Laves phase.The microstructures of the alloys change from an initial single-phase FCC solid solution structure (x=0) to a hypoeutectic microstructure (x=0.25),then to a full eutectic microstructure (x =0.45) and finally to a hypereutectic microstructure (0.5 <x< 1.2).The compressive test results show that the Nb0.45 (x =0.45) alloy with a full eutectic microstructure possesses the highest compressive fracture strength of 2558 MPa and a fracture strain of 27.9%.The CoCrFeNi alloy exhibits an excellent compressive ductility,which can reach 50% height reduction without fracture.The Nb0.25 alloy with a hypoeutectic structure exhibits a larger plastic strain of 34.8%.With the increase of Nb content,increased hard/brittle Laves phase leads to a decrease of the plasticity and increases of the Vickers hardness and the wear resistance.The wear mass loss,width and depth of wear scar of the Nb1.2 (x =1.2) alloy with a hypereutectic structure are the lowest among all alloy systems,indicating that the wear resistance of the Nb1.2 alloy is the best one.