Kinetic Model Heterogeneous Reaction Self-assembly on Nanocomposit Sorbent and Their Peculiarity

• 作者: Kibalnikova Olga V.
• 来源期刊: 化学与化工:英文版
• 学科: 工学
• 关键词: SELF-ASSEMBLY reaction nanocomposit equation N.I.Brensted intercaljacia chromate-mass-spectrometrija metaphos helium
• 年，卷（期）: 2018,（3）
• 页码范围: 124-128
• 页数: 5页
• 分类号: TE

摘要

Kinetic modeling of self-assembly reactions occurring on a nanocomposite with the formation of dimers in a solvent cell and molecular complexes in micelles is presented.In this self-organization occurs due to the synergistic effect,due to a combination of nonvalent interactions.This approach opens up new possibilities in the field of chromatographic and separation technologies related to the analysis of complex mixtures.The coefficientαof the self-assembling processes at the nanocomposite.It is shown thatαcan have different values,for example,for pyridine dimer in cage solvent this coefficient is2.5~3.4.Quantum chemical calculations show that the surface of the nanocomposite is doped with alkaline metal,which restores hydrogen atoms,turning them into H-.This is used in a chromate-mass spectrometer in identify environmental toxicants,the technique of determining metaphase in food products.