Discussion on Tc and Re Mononuclear Carbonyls and Their Isovalentions in Gas Phase

• 作者: Cao Shiwei Qin Zhi Wang Yang
• 来源期刊: 中国科学院近代物理研究所和兰州重离子研究装置年报:英文版
• 学科: 地球科学
• 关键词: calculation. chemistry. NEUTRAL
• 年，卷（期）: 2018,（1）
• 页码范围: 55-56
• 页数: 2页
• 分类号: X13

摘要

Mononuclear Tc and Re carbonyls are the model compounds for the chemical characterization of Bh carbonyls at the single atom chemistry.Our preliminary experiments on the stoichiometry of Re carbonyls in the gas phase deduced that the neutral and the cation species are Re(CO)5 and[Re(CO)6]+,respectively[1].We will report here a theoretical study to confirm their stoichiometry by quantum chemistry calculation.