Laser absorption spectroscopy for high temperature H2O time-history measurement at 2.55 μm during oxidation of hydrogen

• 来源期刊: 中国物理B（英文版）
• 关键词: tunable diode laser absorption spectroscopy H2O time-history profile combustion process reac-tion mechanism
• 年，卷（期）: 2018,（7）
• 页码范围: 428-434
• 页数: 7页
• 语种: 英文
• DOI: 10.1088/1674-1056/27/7/074213

摘要

Concentration time-histories of H2O were measured behind reflected shock waves during hydrogen combustion. Ex-periments were conducted at temperatures of 1117–1282 K, the equivalence ratios of 0.5 and 0.25, and a pressure at 2 atm using a mixture of H2/O2 highly diluted with argon. H2O was monitored using tunable mid-infrared diode laser absorption at 2.55 μm (3920.09 cm?1). These time-histories provide kinetic targets to test and refine reaction mechanisms for hy-drogen. Comparisons were made with the predictions of four detailed kinetic mechanisms published in the last four years. Such comparisons of H2O concentration profiles indicate that the AramcoMech 2.0 mechanism yields the best agreement with the experimental data, while CRECK, San Diego, and HP-Mech mechanisms show significantly poor predictions. Reaction pathway analysis for hydrogen oxidation indicates that the reaction H+OH+M=H2O+M is the key reaction for controlling the H2O formation by hydrogen oxidation. It is inferred that the discrepancy of the conversion percentage from H to H2O among these four mechanisms induces the difference of performance on H2O time-history predictions. This work demonstrates the potential of time-history measurement for validation of large reaction mechanisms.