Importance of ligands on TiO2 nanocrystals for perovskite solar cells

• 来源期刊: 中国物理B（英文版）
• 关键词: TiAc2 TiO2 nanocrystal surface ligand perovskite solar cells
• 年，卷（期）: 2018,（1）
• 页码范围: 92-97
• 页数: 6页
• 语种: 英文
• DOI: 10.1088/1674-1056/27/1/018401

摘要

The fabrication of high-quality electron-selective layers at low temperature is a prerequisite to realizing efficient fl exible and tandem perovskite solar cells (PSCs). A colloidal-quantum-dot ink that contains TiO2 nanocrystals enables the deposition of a fl at film with matched energy level for PSCs; however, the selection of ligands on the TiO2 surface is still unexplored. Here, we systematically studied the effect of the titanium diisopropoxide bis(acetylacetonate) (TiAc2) ligand on the performance of PSCs with a planar n–i–p architecture. We prepared TiO2 nanocrystals from TiCl4 and ethyl alcohol with Cl?ligands attached on its surface and we found that a tiny amount of TiAc2 treatment of as-prepared TiO2 nanocrystals in a mixed solution of chloroform and methyl alcohol can enhance PSC power conversion efficiency (PCE) from 14.7％to 18.3％. To investigate the effect of TiAc2 ligand on PSCs, TiO2 samples with different TiAc2 content were prepared by adding TiAc2 into the as-obtained TiO2 nanocrystal solution. We use x-ray photoelectron spectroscopy to identify the content of Cl so as to reveal that Cl ligands can be substituted by TiAc2. We speculate that the improvement in PCE originates from amorphous TiO2 formation on the TiO2 nanocrystal surface, whereby a single-molecule layer of amorphous TiO2 facilitates charge transfer between the perovskite film and the TiO2 electronic transport layer, but excessive TiAc2 lowers the PSC performance dramatically. We further prove our hypothesis by x-ray diffraction measurements. We believe the PCE of PSCs can be further improved by carefully choosing the type and changing the content of surface ligands on TiO2 nanocrystal.