Effects of filler loading and surface modification on electrical and thermal properties of epoxy/montmorillonite composite

• 来源期刊: 中国物理B（英文版）
• 关键词: modified epoxy resin surface modification electric property thermal property
• 年，卷（期）: 2018,（11）
• 页码范围: 332-339
• 页数: 8页
• 语种: 英文
• DOI: 10.1088/1674-1056/27/11/117806

摘要

Epoxy-based composites containing montmorillonite (MMT) modified by silylation reaction with γ-aminopropyltriethoxysilane (γ-APTES) and 3-(glycidyloxypropyl) trimethoxysilane (GPTMS) are successfully prepared.The effects of filler loading and surface modification on the electrical and thermal properties of the epoxy/MMT composites are investigated.Compared with the pure epoxy resin,the epoxy/MMT composite,whether MMT is surface-treated or not,shows low dielectric permittivity,low dielectric loss,and enhanced dielectric strength.The MMT in the epoxy/MMTcomposite also influences the thermal properties of the composite by improving the thermal conductivity and stability.Surface functionalization of MMT not only conduces to the better dispersion of the nanoparticles,but also significantly affects the electric and thermal properties of the hybrid by influencing the interfaces between MMT and epoxy resin.Improved interfaces are good for enhancing the electric and thermal properties of nanocomposites.What is more,the MMT modified with GPTMS rather than γ-APTES is found to have greater influence on improving the interface between the MMT filler and polymer matrices,thus resulting in lower dielectric loss,lower electric conductivity,higher breakdown strength,lower thermal conductivity,and higher thermal stability.