Experimental Investigation of the Mg-Zn-Zr Isothermal Section at 400 ℃
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摘要:
Mg-Zn-Zr series Mg alloys (ZK) are one of the most important commercial Mg alloys due to their good comprehensive mechanical properties.The phase equilibria of the Mg-Zn-Zr system at 400 ℃ covering the overall composition range were investigated by X-ray diffraction and electron probe microanalyses on thirteen ternary alloys.Three ternary compounds,τ1,τ2 and τ3,were detected to be thermodynamically stable at 400 ℃,and their homogeneity range was determined to be Mg(7-17)Zn(80-88)Zr(4-6),Mg(15-22)Zn(66-68)Zr(9-16) and Mg9Zn68Zr23 (in at.%),respectively.Eight three-phase regions and four two-phase regions were observed.The maximum solubility of Mg in Zn22Zr,Zn39Zr5 and Zn3Zr phases was measured to be 0.52,0.37 and 0.99 at.%,respectively,while the solubility of Zr in MgZn2 and Mg2Zn3 phases is negligible.The isothermal section of the Mg-Zn-Zr system at 400 ℃ was then constructed based on the present experimental data.