Electromagnetic interference shielding properties of polymer derived SiC-Si3N4 composite ceramics

• 来源期刊: 材料科学技术（英文版）
• 年，卷（期）: 2019,（12）
• 页码范围: 2832-2839
• 页数: 8页
• 语种: 英文

摘要

SiC-Si3N4 composite ceramics are successfully fabricated by pyrolysis of ferrocene-modified polycarbosilane (PCS) mixed with inert filler Si3N4 powders,followed by thermal treatment from 1 100 ℃ to 1400 ℃ in Ar atmosphere.The porosity of SiC-Si3 N4 ceramics decreases to 6.4％ due to the addition of inert filler Si3N4.And the content and crystallization degree of free carbon and SiC derived from PCS are improved simultaneously with the increase of thermal treatment temperature.Finally,the free carbon and SiC interconnect,forming the conductive network.As a result,the electromagnetic interference (EMI) shielding performance of the as-prepared ceramic annealed at 1400℃ reaches up to 36dB,meaning more than 99.9％ of EM energy is shielded.The low porosity and high EMI shielding performance enable SiC-Si3N4 composite ceramics to be a promisingelectromagnetic shielding and structural material.