Layered P2-Na0.7MnO2.05 microflakes as a cathode material for high performance sodium-ion batteries

• 作者: GE Xiaoli HUI Xiaobin LIU Xinhe WANG Huiyang YIN Longwei
• 来源期刊: 中国体视学与图像分析
• 学科: 工学
• 年，卷（期）: 2020,（2）
• 所属期刊栏目: 三维定量研究与三维重建
• 页码范围: 101-113
• 页数: 13页
• 分类号: TM912
• 语种: 中文
• DOI: 10.13505/j.1007-1482.2020.25.02.002

摘要

Sodium-ion batteries (SIBs),as the low-cost and large-scale energy storage devices,have attracted wide attention,but their capacity and cycle performance are limited by cathode materials.Here,P2-Na0.7MnO2.05 microflakes with the diameter 500 nm to 1 μm are synthesized by an improved solid-state reaction.The as-prepared P2-Na0.7 MnO2.05 microflakes exhibit excellent electrochemical performance when tested as a cathode material of SIBs.It delivers a considerably reversible capacity of 142.7 mA h g-1 at a current density of 0.3 C (1C =180 mA g-1) with a slow capacity decay to 121.5 mA h g-1 after 50 cycles.Even at a high current density of 2 C,the P2-Na0.7MnO2.05 microflakes still show a specific capacity of 88.9 mA h g-1 with a capacity retention of 75％ after 100 cycles.The above performance of Na0.7MnO2.05 microflakes are better than Na0.7MnO2.05 with large block morphology,which is mainly attributed to the lamellar morphology of P2-Na0.7 MnO2.05 alleviating structural deformation and accelerating reaction kinetics.This strategy will provide new opportunities to develop stable oxide cathodes for SIBs.