The Theory of Conjugate Reactions in the Context of Modern Ideas

• 作者: Tofik Nagiev
• 来源期刊: 化学工程与科学期刊(英文)
• 学科: 物理学
• 关键词: CONJUGATION INTERFERENCE DETERMINANT INITIATION
• 年，卷（期）: 2020,（1）
• 页码范围: 52-68
• 页数: 17页
• 分类号: O57

摘要

Various types of possible interactions between reactions are discussed. Some of them are united by the general idea of chemical reaction interference. The ideas on conjugated reactions are broadened and the determinant formula is deduced;the coherence condition for chemical interference is formulated and associated phase shifts are determined. It is shown how interaction between reactions may be qualitatively and quantitatively assessed and kinetic analysis of complex reactions with under-researched mechanisms may be performed with simultaneous consideration of the stationary concentration method. Using particular examples, interference of hydrogen peroxide dissociation and oxidation of substrates is considered.