Covalent Bonds Creation between Gas and Liquid Phase Change: Compatibility with Covalent and Even-Odd Rules Based on a “Specific Periodic Table for Liquids”

• 作者: Geoffroy Auvert
• 来源期刊: 物理化学期刊(英文)
• 学科: 工学
• 关键词: COVALENT Bond Even-Odd Rule LIQUID GAS Periodic Table MOLECULE Association DISSOCIATION
• 年，卷（期）: wlhxqkyw_2020,（1）
• 页码范围: 68-85
• 页数: 18页
• 分类号: TG1

摘要

A decrease in temperature will eventually turn a gas into liquid and then into a solid. Each of these phase change shows a higher degree in cohesion of molecules. While it is usually admitted that molecules in solids form additional connections, the cohesion of molecules in liquids is usually explained by changes in kinetics of molecules. Given that the density of a solid is nearly the same than that of a liquid, the present paper assumes a different stand and considers that connections between molecules must be similar in liquids and in solids. The difference between gas, in which molecules are entirely loose, and liquid, is therefore the presence of an additional connection between gaseous molecules. This paper describes how and where these connections are built with the help of a few rules and a “specific periodic table for liquids”. The coherence of this approach is reinforced by its capacity to explain phase change of forty well-known molecules containing inorganic and organic elements.