Interpretation of Adsorption Thermodynamics and Kinetics

• 作者: Donbebe Wankasi
• 来源期刊: 物理化学期刊(英文)
• 学科: 化学
• 关键词: Gibbs Free Energy Entropy Change Adsorption Density Sticking Probability Activation Energy Pseudo-Second-Order Kinetic Model Elovich Model Brouers-Sotolongo Fractal Kinetic Model
• 年，卷（期）: wlhxqkyw_2020,（3）
• 页码范围: 166-182
• 页数: 17页
• 分类号: O64

摘要

A complete study of adsorption processes will be less complete if the structure and dynamics of its different elements and how they interact is not well captured. Therefore, the extensive study of adsorption thermodynamics in conjunction with adsorption kinetics is inevitable. Measurable thermodynamic </span><span style="font-family:Verdana;">properties such as temperature equilibrium constant and their non-measurable</span><span style="font-family:Verdana;"> counterparts such as Gibbs free energy change, enthalpy, entropy etc. are very important design variables usually deployed for the evaluation and prediction of the mechanism of adsorption processes.