Hydro-geochemistry evolution in Ordovician limestone water induced by mountainous coal mining: A case study from North China
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摘要:
This research aimed to investigate the changing mechanism of hydro-geochemistry in Ordovician limestone karst (OL) water induced by mountainous coal mining activities.Thus,the hydrogeochemistry evolution of OL water over 40 years within a typical northern mountainous coal mine named Fengfeng Mine was studied by using Piper diagram,Gibbs scheme,ions correlation and Principal component analysis (PCA) methods.Results showed that,except for HCO3-,the ions of Ca2+,Mg2+,SO42-,Na++K+,Cl-and total dissolution solids (TDS) values all increased by years as mining continues.Different hydro-geochemical characteristics in different periods can reflect different water-rock interactions.Accordingly,sulfates dissolution gradually took place of carbonates in water-rock interaction.Especially,OL water-rock interactions in different periods were all affected by rock weathering and evaporationconcentration together.At last,evaporationconcentration co-effect dominated the hydrogeochemistry evolution slowly,along with significant cations exchange over years.