Development of Single-Molecule Magnets

• 作者: Dong Shao Xin-Yi Wang
• 来源期刊: 中国化学（英文版）
• 年，卷（期）: 2020,（9）
• 所属期刊栏目: Critical Review
• 页码范围: 1005-1018
• 页数: 14页
• 语种: 英文
• DOI: 10.1002/cjoc.202000090

摘要

Single-molecule magnets (SMMs) are paramagnetic molecules that can be magnetized below a certain temperature and have potential applications in high-density information storage, magnetic qubits, spintronic devices, etc.The discovery of the first SMM, Mn12, opened a new era of molecular magnetism and promoted collaborative researches between chemists and physicists for their exotic quantum as well as classical magnetic properties.In the recent past, great efforts have been made to develop strategies for constructing new SMMs with high energy barriers (Ueff) and blocking temperatures (TB), resulting in great and fast development of SMMs.In this concise review, we highlight the main synthetic approaches and representative results in the design and synthesis of high performance SMMs.We hope to give the readers a basic understanding of SMMs and a snapshot of the representative researches on SMMs from a perspective of synthetic chemists.