N-Heterocyclic Carbene Organocatalysis: Activation Modes and Typical Reactive Intermediates

• 作者: Hongling Wang Xingkuan Chen Yonggui Robin Chi Zhichao Jin
• 来源期刊: 中国化学（英文版）
• 年，卷（期）: 2020,（10）
• 所属期刊栏目: J&K Critical Review
• 页码范围: 1167-1202
• 页数: 36页
• 语种: 英文
• DOI: 10.1002/cjoc.202000107

摘要

Contents 1.Introduction 1168 1.1.General structures of N-heterocyclic carbenes 1168 1.2.General properties of N-heterocyclic carbenes 1168 1.3.Major applications of NHCs in organocatalysis 1169 2.Activation of Aldehydes for Access to Breslow and Homoenolate Intermediates 1169 2.1.Characterization of the Breslow intermediate 1169 2.2.Progresses in the benzoin and Stetter reactions 1170 2.3.Hydroacylation of alkenes and alkynes 1172 2.4.Annulation reactions of homoenolate intermediates 1174 2.5.Non-annulation reactions of homoenolate intermediates 1175 2.6.Cooperative catalysis with NHC-bounded homoenolate intermediates 1176 3.Activation of Ketenes and Aldehydes for Access to Enolate, Dienolate, and α,β-Unsaturated Acylazolium Intermediates 1177 3.1.Activation of ketenes for access to enolate intermediates 1177 3.2.Activation of ketenes for access to dienolate intermediates 1178 3.3.Activation of aldehydes for access to enolate intermediates 1178 3.4.Activation of aldehydes for access to dienolate intermediates 1180 3.5.Activation of aldehydes for access to α,β-unsaturated acyl azolium intermediates 1181

作者信息

序号	姓名	单位	发文数	被引次数	H指数	G指数
1	Xingkuan Chen		1	0	0.0	0.0
2	Hongling Wang		1	0	0.0	0.0
3	Zhichao Jin		1	0	0.0	0.0
4	Yonggui Robin Chi		1	0	0.0	0.0