Broadband perovskite quantum dot spectrometer beyond human visual resolution

• 作者: Xiaoxiu Zhu Liheng Bian Hao Fu Lingxue Wang Bingsuo Zou Qionghai Dai Jun Zhang Haizheng Zhong
• 来源期刊: 光：科学与应用（英文版）
• 年，卷（期）: 2020,（3）
• 所属期刊栏目: Original Articles
• 页码范围: 730-738
• 页数: 9页
• 语种: 英文

摘要

The quantum dot spectrometer, fabricated by integrating different quantum dots with an image sensor to reconstruct the target spectrum from spectral-coupled measurements, is an emerging and promising hyperspectrometrytechnology with high resolution and a compact size. The spectral resolution and spectral range of quantum dot spectrometers have been limited by the spectral variety of the available quantum dots and the robustness of algorithmic reconstruction. Moreover, the spectrometer integration of quantum dots also suffers from inherent photoluminescence emission and poor batch-to-batch repeatability. In this work, we developed nonemissive in situ fabricated MA3Bi2X9 and Cs2SnX6 (MA=CH3NH3;X=Cl, Br, I) perovskite-quantum-dot-embedded films (PQDFs) with precisely tunable transmittance spectra for quantum dot spectrometer applications. The resulting PQDFs contain in situ fabricated perovskite nanocrystals with homogenous dispersion in a polymeric matrix, giving them advantageous features such as high transmittance efficiency and good batch-to-batch repeatability. By integrating a filter array of 361 kinds of PQDFs with a silicon-based photodetector array, we successfully demonstrated the construction of a perovskite quantum dot spectrometer combined with a compressive-sensing-based total-variation optimization algorithm. A spectral resolution of～1.6 nm was achieved in the broadband of 250–1000 nm. The performance of the perovskite quantum dot spectrometer is well beyond that of human eyes in terms of both the spectral range and spectral resolution. This advancement will not only pave the way for using quantum dot spectrometers for practical applications but also significantly impact the development of artificial intelligence products, clinical treatment equipment, scientific instruments, etc.