A Sulfonate-based Metal-organic Framework for the Transformation of CO2 and Epoxides into Cyclic Carbonates

• 作者: HUANG Ge LI Tao LIU Tian-Fu XUE Huan YIN Qi
• 来源期刊: 结构化学
• 年，卷（期）: 2020,（11）
• 所属期刊栏目: coordination chemistry
• 页码范围: 2027-2032
• 页数: 6页
• 语种: 英文
• DOI: 10.14102/j.cnki.0254-5861.2011-2741

摘要

An interesting metal-organic framework (MOF) PFC-31 was synthesized by a simple solvothermal reaction.X-ray crystallography reveals that PFC-31 crystallizes in monoclinic system,space group P21/c with a =6.8410(17),b =20.123(5),c =7.689(2) (A),β =104.239(7)°,V=1026.0(5) (A)3,Z=2,C16H22CuN4OsS2,Mr =526.03,μ =1.322 mm-1,Dc =1.703 g/cm3,F(000) =542,GOOF =1.214,R =0.0975 and wR =0.2324.According to X-ray analysis,PFC-31 shows one-dimensional chain constructed by Cu(Ⅱ) centers coordinating with two pyridine groups,two sulfonate groups and two DMF molecules.Owing to the orderly functionalized sulfonate group and Lewis metal sites,PFC-31 exhibits good catalytic capability for CO2 cycloaddition of epoxide under normal pressure and temperature.

作者信息

序号	姓名	单位	发文数	被引次数	H指数	G指数
1	XUE Huan	中国科学院福建物质结构研究所	1	0	0.0	0.0
2	LI Tao	中国科学院福建物质结构研究所	1	0	0.0	0.0
3	YIN Qi	中国科学院福建物质结构研究所	2	0	0.0	0.0
4	HUANG Ge	中国科学院福建物质结构研究所	1	0	0.0	0.0
5	LIU Tian-Fu	中国科学院福建物质结构研究所	1	0	0.0	0.0