Synthesis of black phosphorus structured polymeric nitrogen?

• 作者: Caoping Niu Haipeng Su Junran Zhang Xianlong Wang Yanchun Li Ying Liu Zhongxue Ge
• 来源期刊: 中国物理B（英文版）
• 年，卷（期）: 2020,（10）
• 所属期刊栏目: CONDENSED MATTER: STRUCTURAL, MECHANICAL, AND THERMAL PROPERTIES
• 页码范围: 498-503
• 页数: 6页
• 语种: 英文
• DOI: 10.1088/1674-1056/aba9bd

摘要

Since the discoveries of polymeric nitrogen, named cg-N (2004), LP-N (2014), HLP-N (2019), another polymorph named black phosphorus nitrogen (BP-N) was synthesized at high-pressure-high-temperature conditions. The narrow ex-isting pressure region and similar synthesized pressure of BP-N compared with cg-N indicate that the stable energy and enthalpy of formation of these two structures are close to each other, which was confirmed by our theoretical calculation. In order to obtain the pressure region of BP-N phase, pure N2 and TiN/Pb + N2 precursors were used for laser-heating high pressure experiments in diamond anvil cell (DAC), and the phase identity was examined by Raman and XRD mapping. BP-N can be synthesized in the pressure range of 130 GPa to 140 GPa with the assistance of heating absorber. With the de-crease of the pressure, BP-N can be quenched to ～ 40 GPa. The synthesizing pressure–temperature and the stable pressure region of BP-N are important for further exploration of BP-N and its kinetic and thermal dynamic relationship with other polymeric nitrogen, especially cg-N.