College English teaching based on SPOC + double teacher teaching mode is popular with more and more English teachers because of its technology and interconnection, and it is widely used in College English teaching class. This paper takes college English listening course as an example, and divides it into experimental group and control group, respectively based on SPOC + double teacher teaching mode and traditional teaching method. The results show that SPOC + double teacher teaching mode can improve students' English listening performance. At the same time, students'satisfaction with SPOC + double teacher teaching mode is higher than that of traditional listening teaching.