Regioselective B-H/C-H Bond Activation at Azo-Substituted Carboranes Induced by Half-Sandwich Iridium(Ⅲ) Complex

• 作者: Peng-Fei Cui Yang Gao Shu-Ting Guo Guo-Xin Jin
• 来源期刊: 中国化学（英文版）
• 年，卷（期）: 2021,（2）
• 所属期刊栏目: Concise Reports
• 页码范围: 281-287
• 页数: 7页
• 语种: 英文
• DOI: 10.1002/cjoc.202000461

摘要

We report herein a practical approach for regio-selective B-H/C-H bond activation at azo-substituted carboranes.The reaction proceeded through Iridium(Ⅲ)-induced selective B-H/C-H bond activations based on an azo directing group.Through this strategy,a series of mononuclear,trinuclear and tetranuclear cyclometalated iridium complexes containing Cp*Ir-B or Cp*Ir-C bonds were successfully isolated in a high yield.In this work,efficient routes are developed through one-pot reactions to prepare polynuclear organometallic complexes.