Effect of LaPO4 Introduction as a Vanadium Trap for Preventing USY Zeolite Destruction

• 来源期刊: 中国炼油与石油化工（英文版）
• 年，卷（期）: 2021,（1）
• 所属期刊栏目: Catalyst Research
• 页码范围: 53-57
• 页数: 5页
• 语种: 英文

摘要

The use of lanthanum phosphate as a vanadium trap for preventing destruction of USY zeolite was studied. The effect of deposited vanadium on the hydrothermal destruction of zeolite was investigated by the solid-state NMR technique. LaPO4 species can inhibit the zeolite framework structure from being collapsed by vanadium after steaming treatment. The EPR results show the oxidation-reduction reaction in LaPO4 and V2O5 system and inhibition of zeolite destruction by V5+. The catalysts prepared from USY and LaPO-USY zeolites were also tested in the catalytic reactions of heavy oil. The assessment results indicated that the USY modified with LaPO4 could bring about remarkably high dehydrogenation ability.