Chiral Spirocyclic Phosphoric Acids and Their Growing Applications

• 作者: Xufeng Lin Lei Wang Zhao Han Zhouli Chen
• 来源期刊: 中国化学（英文版）
• 年，卷（期）: 2021,（4）
• 所属期刊栏目: Chemistry Authors Up Close
• 页码范围: 802-824
• 页数: 23页
• 语种: 英文
• DOI: 10.1002/cjoc.202000446

摘要

Chiral spirocyclic phosphoric acids (SPAs) are introduced in 2010 and have been versatile catalysts capable of promoting a wide range of asymmetric organocatalytic reactions,such as multi-component reactions,Friedel-Crafts reactions,Pictet-Spengler reactions,Fisch-er indolizations,cycloaddition reactions,desymmetrization reac-tions,dearomatization reactions,conjugate addition reactions and rearrangement reactions,etc.Moreover,a diverse range of applica-tions in metal-organic cooperative catalysis,organic photoredox catalysis,total synthesis,materials science and molecular recogni-tion are beautifully illustrated.This account summarizes the past decade's advances in this field and highlights the selected but not comprehensive significant achievements.