The complexity of the Portevin-Le Chatelier (PLC) effect in an Al alloy at different temperatures was ana- lyzed by modified multiscale entropy. The results show that three evolutions of entropy with scale factor, i.e., near zero, monotonically increasing and peak-shape, were observed corresponding to the smooth curves, type-A serrations and type-B/-C serrations, respectively. The scale factor at the peak was one- third of the average serration period. The sample entropy increased initially and then decreased with temperature, which was opposite to the critical strain. It is also suggested that the type-A serrations cor- responded to self-organized criticality and the type-B/-C serrations corresponded to chaos through the evolutions of entropy with scale factor.