The mechanodonor-acceptor coupling(MDAC)approach for uni-directional multi-state fluorochromism

• 作者: Luyan Gu Lujia Zhang Xiao Luo Ying Zheng Zhiwei Ye Meng Lv Jinquan Chen Chunlai Chen Yi Xiao Weihong Zhu Xuhong Qian Youjun Yang
• 来源期刊: 中国科学：化学（英文版）
• 年，卷（期）: 2021,（2）
• 所属期刊栏目: ARTICLES
• 页码范围: 253-262
• 页数: 10页
• 语种: 英文

摘要

Uni-directional multi-state fluorochromic scaffolds are valuable photofunctional molecules and yet scarce.We report a general approach for their design,i.e.,mechanodonor-acceptor coupling(MDAC).A photochromic molecule is a mechanodonor,due to its capability to convert photonic energy into mechanical force.Upon proper coupling,it can be used to drive a mechanochromic molecule for uni-directional multi-state fluorochromism.The embodiment of this approach is a rhodamine-dithienylethylene hydride(RDH),which has been successfully employed in super-resolution localization microscopy