Electrospun Supramolecular Hybrid Microfibers from Conjugated Polymers:Color Transformation and Conductivity Evolution

• 作者: Wei Xue Man Xu Meng-Na Yu Hua-Min Sun Jin-Yi Lin Rong-Cui Jiang Ling-Hai Xie Nai-En Shi Wei Huang
• 来源期刊: 高分子科学（英文版）
• 年，卷（期）: 2021,（7）
• 所属期刊栏目: ARTICLES
• 页码范围: 824-830
• 页数: 7页
• 语种: 英文

摘要

A type of novel electrospun supramolecular hybrid microfibers comprising poly(9-(4-(octyloxy)-phenyl)-2,7-fluoren-9-ol)(PPFOH)and poly(N-vinylcarbazole)(PVK)are successfully prepared for intriguing multi-color emission properties.The supramolecular tunable PPFOH aggregation in PVK matrix endows the complex with a smart energy transfer behavior to obtain the multi-color emissions.In stark contrast to PVK fibers,the emission color of PPFOH/PVK fibers with an efficient dispersion of PPFOH fluorophores at a proper dope ratio can be tuned in a wide spectrum of blue(0.1％),sky blue(0.5％),nearly white(1％),cyan(2％),green(5％)and yellow(10％).Besides,conductive behaviors of the microfiber were demonstrated in accompany with the increment of the doping ratio of PPFOH to PVK.Successful fabrication of polymer light-emitting diode(PLED)based on the blended electrospun fiber provided a further evidence of its excellent electrical property for potential applications in optoelectronic devices.