As a two-dimensional (2D) material,graphene shows excellent advantages in the field of gas sensors due to its inherent large specific surface area and unique elec-trical properties.However,in the practical application of gas detection,graphene sheet is easy to form irreversible agglomeration and has some limitations such as low sen-sitivity,long response time and slow recovery speed,which greatly reduce its gas sensing performance.As a gas sensing material,three-dimensional (3D) porous graphene has been extensively studied in recent years owing to its larger specific surface area and stable structure.In order to synthesize graphene with different three-dimensional structures,many methods have been developed.Herein,the synthesis and assembly of three-dimensional graphene and its composites were reviewed,with emphasis on the application of three-dimensional graphene and its com-posites in the field of gas sensors.The challenges and development prospects of three-dimensional graphene materials in the application of gas sensors were briefly described.