Corrosion behaviour of NiCrFeAl-hBN seal coatings in oxidation environments at a high temperature

• 作者: Su-Yuan Yang Dan Guo Xing-Wang Cheng Jian-Ming Liu Yue-Guang Yu
• 来源期刊: 稀有金属（英文版）
• 年，卷（期）: 2021,（1）
• 所属期刊栏目: ORIGINAL ARTICLES
• 页码范围: 212-218
• 页数: 7页
• 语种: 英文

摘要

The purpose of this investigation was to evaluate the microstructure,high-temperature oxidation behaviour,and hardness of a seal coating under controlled exposures at 750℃with different exposure times.The results reveal that the main phases in the coating are Ni,FeNi3,and hexagonal BN,with α-Al2O3 peaks appearing after 2-h oxidation.As the exposure time increases,the diffraction peak intensity of α-Al2O3 begins to decrease and Cr2O3 peaks appear after 200 h.After 1000 h,Cr2O3 becomes dominant with only small amounts of α-Al2O3 remaining.The high-temperature oxidation process of the coating includes three stages:the fast stage,transition stage,and slow stage.The oxidation rate is constant in each stage,and in the fast stage and slow stages with values of 7.59×10-4 and 8.37×10-5 mg2·cm-4·s-1,respec-tively.Initially,α-Al2O3 forms near the pores in the coat-ing,followed by the formation of Cr2O3.As the exposure time increases,oxidation penetrates into the interior of the coating along phase boundaries to form island-shaped inner oxide layers with high concentrations of Cr,Ni,and Fe.Additionally,hardness increases with increasing oxide percentage.