Porous nitrogen-enriched hollow carbon nanofibers as freestanding electrode for enhanced lithium storage

• 作者: Xiaosa Xu Yuqian Qiu Jianping Wu Baichuan Ding Qianhui Liu Guangshen Jiang Qiongqiong Lu Jiangan Wang Fei Xu Hongqiang Wang
• 来源期刊: 中国化学工程学报（英文版）
• 年，卷（期）: 2021,（4）
• 所属期刊栏目: Energy, Resources and Environmental Technology
• 页码范围: 416-422
• 页数: 7页
• 语种: 英文

摘要

One-dimensional porous carbons bearing high surface areas and sufficient heteroatom doped functional-ities are essential for advanced electrochemical energy storage devices, especially for developing free-standing film electrodes. Here we develop a porous, nitrogen-enriched, freestanding hollow carbon nanofiber (PN-FHCF) electrode material via filtration of polypyrrole (PPy) hollow nanofibers formed by in situ self-degraded template-assisted strategy, followed by NH3-assisted carbonization. The PN-FHCF retains the freestanding film morphology that is composed of three-dimensional networks from the entanglement of 1D nanofiber and delivers 3.7-fold increase in specific surface area (592 m2·g-1) com-pared to the carbon without NH3 treatment (FHCF). In spite of the enhanced specific surface area, PN-FHCF still exhibits comparable high content of surface N functionalities (8.8％, atom fraction) to FHCF. Such developed hierarchical porous structure without sacrificing N doping functionalities together enables the achievement of high capacity, high-rate property and good cycling stability when applied as self-supporting anode in lithium-ion batteries, superior to those of FHCF without NH3 treatment.