Photoinduced Reversible Solid-to-Liquid Transitions and Directional Photofluidization of Azobenzene-containing Polymers

• 作者: Shuo-Feng Liang Chen Nie Jie Yan Qi-Jin Zhang Si Wu
• 来源期刊: 高分子科学（英文版）
• 年，卷（期）: 2021,（10）
• 所属期刊栏目: FEATURE ARTICLES
• 页码范围: 1225-1234
• 页数: 10页
• 语种: 英文

摘要

Photoinduced reversible liquefaction and solidification of polymers enable processing and healing of polymers with light.Some azobenzene-containing polymers (azopolymers) exhibit two types of photoinduced liquefaction properties:photoinduced reversible solid-to-liquid transition and directional photofluidization.For the first type,light switches the glass transition temperature (Tg) values of azopolymers and induces reversible solid-to-liquid transitions.For the second type,polarized light guides solid azopolymers to flow along the polarization direction.Here,we compare the two types of photoliquefaction and discuss their mechanisms.Recent progresses and applications based on photoliquefaction of azopolymers are also highlighted.