High-alloyed superalloy U720Li is difficult to be processed through the conventional cast and wrought route.Boron is an important strengthening element for superal-loys,but the role of boron in the hot ductility of U720Li alloy is not clear.This study is focused on the effect of boron addition,in the range of<0.0005 wt%-0.0240 wt%,on the microstructure and hot ductility behavior of superalloy U720Li.It is found that boron addition significantly increases the content of eutectic(γ+γ')and greatly affects the degree of continuity of the grain boundary eutectic(γ+γ')precipitation.Boron addition dramatically worsens the 1100℃tensile ductility of conventional cast U720Li alloy and causes a change in tensile fracture mode from transgranular to intergranular.The eutectic(γ+γ')represents the most effective site for crack initiation.Boron deteriorates the hot ductility mainly by promoting the continuous precipitation of eutectic(γ+γ')along the grain boundary.