A series of hexagonal phase NaBiF4∶ xYb3+,yEr3+ were successfully synthesized by solvothermal method.The morphology,phase structure,up-conversion luminescence and down-conversion luminescence proper-ties of Yb3+ and Er3+ doping concentration and the energy transfer mechanism were studied.It shows that the doping of Yb3+ and Er3+ does not cause the phase transition of NaBiF4,but influences its morphology.In the NaBiF4∶Yb3+,Er3+,Yb3+ can transfer energy with Er3+,enhanc-ing up-conversion green emission.With Yb3+ doping concentration increasing,the up-conversion red-green ratio will increase while the down-conversion intensity of the green emission decreases and that of the red emission increases.Considering the potential application of NaBiF4∶xYb3+,yEr3+ phosphors in optical illumination,the ther-mal stability was carried out.