Interference from HONO in the measurement of ambient air NO2 via photolytic conversion and quantification of NO

• 作者: Nicholas J.Gingerysty Charles A.Odame-Ankrah Nick Jordan Hans D.Osthoff
• 来源期刊: 环境科学学报（英文版）
• 年，卷（期）: 2021,（9）
• 所属期刊栏目: Regular articles
• 页码范围: 184-193
• 页数: 10页
• 语种: 英文

摘要

The reference method to quantify mixing ratios of the criteria air pollutant nitrogen diox-ide (NO2) is NO-O3 chemiluminescence (CL), in which mixing ratios of nitric oxide (NO) are measured by sampling ambient air directly, and mixing ratios of NOx (= sum of NO and NO2) are measured by converting NO2 to NO using, for example, heated molybdenum catalyst or, more selectively, photolytic conversion (P-CL). In this work, the nitrous acid (HONO) inter-ference in the measurement of NO2 by P-CL was investigated. Results with two photolytic NO2 converters are presented. The first used radiation centered at 395 nm, a wavelength region commonly utilized in P-CL. The second used light at 415 nm, where the overlap with the HONO absorption spectrum and hence its photolysis rate are less. Mixing ratios of NO2, NOx and HONO entering and exiting the converters were quantified by Thermal Dissociation Cavity Ring-down Spectroscopy (TD-CRDS). Both converters exhibited high NO2 conversion efficiency (CFNO2;>90％) and partial conversion of HONO. Plots of CF against flow rate were consistent with photolysis frequencies of 4.2 s-1 and 2.9 s-1 for NO2 and 0.25 s-1 and 0.10 s- 1 for HONO at 395 nm and 415 nm, respectively. CFHONO was larger than predicted from the overlap of the emission and HONO absorption spectra. The results imply that measure-ments of NO2 by P-CL marginally but systematically overestimate true NO2 concentrations, and that this interference should be considered in environments with high HONO:NO2 ra-tios such as the marine boundary layer or in biomass burning plumes.