Chiral Coordination Metallacycles/Metallacages for Enantioselec-tive Recognition and Separation

• 作者: Liyan Zhang Huiping Liu Guozan Yuan Ying-Feng Han
• 来源期刊: 中国化学（英文版）
• 年，卷（期）: 2021,（8）
• 所属期刊栏目: Recent Advances
• 页码范围: 2273-2286
• 页数: 14页
• 语种: 英文
• DOI: 10.1002/cjoc.202100180

摘要

In recent years,chiral discrete supramolecular coordination complexes have attracted increasing interest as simple enzyme mimetics owing to their aesthetic architectures and potential applications in chiral science.This review summarizes the recent advances on chiral coordination metallacy-cles/metallacages with inherent cavities for enantionselective recognition and separation,including their design principles and synthesis,the introduc-tion of chirality and functionality,structural adaptability,and host-guest bonding in enantioselective process.Finally,the perspectives on the remain-ing challenges and future opportunities are presented.