Durable self-polishing antifouling Cu-Ti coating by a micron-scale Cu/Ti laminated microstructure design

• 作者: Jiajia Tian Kangwei Xu Junhua Hu Shijie Zhang Guoqin Cao Guosheng Shao
• 来源期刊: 材料科学技术（英文版）
• 年，卷（期）: 2021,（20）
• 页码范围: 62-74
• 页数: 13页
• 语种: 英文

摘要

Marine biofouling is a major issue deteriorating the service performance and lifespan of marine infrastruc-tures.The development of a durable,long-term,and environment-friendly antifouling coating is therefore of significant importance but still a critical challenge in maritime engineering.Herein,we developed a Cu-Ti composite antifouling coating with micron-sized alternating laminated-structure of Cu/Ti by plasma spraying of mechanically mixed Cu/Ti powders.The coating was designed to enable controlled release of Cu ions through galvanic dissolution of Cu laminates from the Cu/Ti micro-galvanic cell in aqueous solution.Results showed that remarkable antifouling efficiency against bacterial survival and adhesion up to ～100 ％ was achieved for the Cu-Ti coating.Cu/Ti micro-galvanic cell was in-situ formed within Cu-Ti coating and responsible for its Cu ions release.The successive dissolution of Cu laminates resulted in the formation of micro-channels under Ti laminates near surface,which contributed to controlled slow Cu ions release and self-polishing effect.Thus,environment-friendly antifouling capability and ～200 ％longer antifouling lifetime than that of the conventional organic antifouling coatings can be achieved for the Cu-Ti coating.On the other hand,as compared to the conventional organic antifouling coatings,the Cu-Ti composite coating presented much higher mechanical durability due to its strong adhesion strength,excellent mechanical properties,and two orders lower wear rate.The present laminated Cu-Ti coating exhibits combination of outstanding antifouling performance and high mechanical durability,which makes this coating very potentially candidates in marine antifouling application.