Single-atom catalysts for metal-sulfur batteries:Current progress and future perspectives

• 作者: Ru Xiao Ke Chen Xiaoyin Zhang Zhenzhen Yang Guangjian Hu Zhenhua Sun Hui-Ming Cheng Feng Li
• 来源期刊: 能源化学
• 年，卷（期）: 2021,（3）
• 页码范围: 452-466
• 页数: 15页
• 语种: 英文

摘要

Metal-sulfur batteries are recognized as a promising candidate for next generation electrochemical energy storage systems owing to their high theoretical energy density,low cost and environmental friendliness.However,sluggish redox kinetics of sulfur species and the shuttle effect lead to large polar-ization and severe capacity decay.Numerous approaches from physical barrier,chemical adsorption strategies to electrocatalysts have been tried to solve these issues and pushed the rate and cycle perfor-mance of sulfur electrodes to higher levels.Most recently,single-atom catalysts(SACs)with high cat-alytic efficiency have been introduced into metal-sulfur systems to achieve fast redox kinetics of sulfur conversion.In this review,we systematically summarize the current progress on SACs for sulfur elec-trodes from aspects of synthesis,characterization and electrochemical performance.Challenges and Dotential solutions for designing SACs for high-performance sulfur electrodes are discussed.