Guest ions pre-intercalation strategy of manganese-oxides for supercapacitor and battery applications

• 作者: Lina Chen Chongyang Hao Yamin Zhang Youri Wei Linna Dai Jun Cheng Hongqiang Zhang Lijie Ci
• 来源期刊: 能源化学
• 年，卷（期）: 2021,（9）
• 页码范围: 480-493
• 页数: 14页
• 语种: 英文

摘要

Optimization of intrinsic structure of electrode materials plays decisive roles in promoting the develop-ment of energy storage systems to meet the fast-growing requirements in the market.Interlayer engi-neering has been proved to be an effective way to obtain adequate active sites,preferable ion diffusion channels and stable structure,thus enhance the performance of batteries.An in-depth understanding of the correlation among synthesis,structure and performance will significantly promote the develop-ment of excellent materials and energy storage devices.Therefore,in this review,recent advances in regards to cation preintercalation engineering in Mn-based electrode materials for rechargeable metal ion batteries are systematically summarized.Preintercalated guest cations can expand interlayer space to promote ion diffusion kinetics,serve as pillars to stabilize structure,control composition and valence to switch electrochemical behavior,thus improve the overall performance of secondary batteries.Moreover,the existing challenges and perspectives are provided for the interlayer engineering and its promotion to battery industry.