A simple method to synthesize worm-like AlN nanowires and its field emission studies

• 作者: Qi Liang Meng-Qi Yang Chang-Hao Wang Ru-Zhi Wang
• 来源期刊: 中国物理B（英文版）
• 年，卷（期）: 2021,（8）
• 所属期刊栏目: CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES
• 页码范围: 534-540
• 页数: 7页
• 语种: 英文
• DOI: 10.1088/1674-1056/abe3e7

摘要

The worm-like AlN nanowires are fabricated by the plasma-enhanced chemical vapor deposition (PECVD) on Si substrates through using Al powder and N2 as precursors,CaF2 as fluxing medium,Au as catalyst,respectively.The as-grown worm-like AlN nanowires each have a polycrystalline and hexagonal wurtzite structure.Their diameters are about 300 nm,and the lengths are over 10 μm.The growth mechanism of worm-like AlN nanowires is discussed.Hydrogen plasma plays a very important role in forming the polycrystalline structure and rough surfaces of worm-like AlN nanowires.The worm-like AlN nanowires exhibit an excellent field-emission (FE) property with a low turn-on field of 4.5 V/μm at a current density of 0.01 mA/cm2 and low threshold field of 9.9 Wμm at 1 mA/cm2.The emission current densities of worm-like AlN nanowires each have a good stability.The enhanced FE properties of worm-like AlN nanowires may be due to their polycrystalline and rough structure with nanosize and high aspect ratio.The excellent FE properties of worm-like AlN nanowires can be explained by a grain boundary conduction mechanism.The results demonstrate that the worm-like AlN nanowires prepared by the proposed simple and the PECVD method possesses the potential applications in photoelectric and field-emission devices.