Quantifying plasmon resonance and interband transition contributions in photocatalysis of gold nanoparticle

• 作者: Liang Dong Chengyun Zhang Lei Yan Baobao Zhang Huan Chen Xiaohu Mi Zhengkun Fu Zhenglong Zhang Hairong Zheng
• 来源期刊: 中国物理B（英文版）
• 年，卷（期）: 2021,（7）
• 所属期刊栏目: CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC,AND OPTICAL PROPERTIES
• 页码范围: 519-524
• 页数: 6页
• 语种: 英文
• DOI: 10.1088/1674-1056/abfa0c

摘要

Localized surface plasmon has been extensively studied and used for the photocatalysis of various chemical reactions.However,the different contributions between plasmon resonance and interband transition in photocatalysis has not been well understood.Here,we study the photothermal and hot electrons effects for crystal transformation by combining con-trolled experiments with numerical simulations.By photo-excitation of NaYF4:Eu3+@Au composite structure,it is found that the plasmonic catalysis is much superior to that of interband transition in the experiments,owing to the hot electrons generated by plasmon decay more energetic to facilitate the reaction.We emphasize that the energy level of hot electrons plays an essential role for improving the photocatalytic activity.The results provide guidelines for improving the efficiency of plasmonic catalysis in future experimental design.