Carbonized wood with ordered channels decorated by NiCo2O4 for lightweight and high-performance microwave absorber

• 作者: Guangyu QIN Xiaoxiao HUANG Xu YAN Yunfei HE Yuhao LIU Long XIA Bo ZHONG
• 来源期刊: 先进陶瓷（英文版）
• 年，卷（期）: 2022,（1）
• 所属期刊栏目: Research Article
• 页码范围: 105-119
• 页数: 15页
• 语种: 英文

摘要

Wood-derived carbon has a 3D porous framework composed of through channels along the growth direction,which is a suitable matrix for preparing electromagnetic wave(EMW)absorbing materials with low cost,light weight,and environmental friendliness.Herein,the carbonized wood decorated by short cone-like NiCo2O4(NiCo2O4@CW)with highly ordered straight-channel architecture was successfully manufactured through a facile calcination procedure.The horizontal arrangement of the through channels of NiCo2O4@CW(H-NiCo2O4@CW)exhibits a strong reflection loss value of-64.0 dB at 10.72 GHz with a thickness of 3.62 mm and a low filling ratio of 26 wt％(with the density of 0.98 g·cm-3),and the effective absorption bandwidth(EAB)is 8.08 GHz(9.92-18.0 GHz)at the thickness of 3.2 mm.The excellent microwave absorption(MA)property was ascribed to the ordered-channel structure with abundant interfaces and defects from NiCo2O4@CW,which could promote the interfacial polarization and dipole polarization.What is more,this advantageous structure increased the multiple reflections and scattering.Finite element analysis(FEA)simulation is carried out to detect the interaction between the prepared material and EMW when the ordered channels are arranged in different directions.This research provides a low-cost,sustainable,and environmentally friendly strategy for using carbonized wood to fabricate microwave absorbers with strong attenuation capabilities and light weight.