Chain-transfer-catalyst:strategy for construction of site-specific functional CO2-based polycarbonates

• 作者: Enhao Wang Shunjie Liu Han Cao Chunwei Zhuo Xianhong Wang Fosong Wang
• 来源期刊: 中国科学：化学（英文版）
• 年，卷（期）: 2022,（1）
• 所属期刊栏目: ARTICLES
• 页码范围: 162-169
• 页数: 8页
• 语种: 英文

摘要

Site-specific functional polymers are generally synthesized from functionalized chain transfer agents (CTA) in the presence of catalysts.However,the poor solubility or chemical inertness of CTAs may make polymerizations uncontrollable.Now,this issue is addressed by proposing a strategy of designing chain-transfer-catalyst (CTC) that combines catalyst and CTA into one.The occurrence of catalytic effect naturally triggers the chain transfer process to give catalyst-labeled polymers with well-defined structures.As a proof-of-concept,cobalt(Ⅲ) porphyrin catalysts with one,two and four hydroxyl groups act as efficient CTCs,giving the corresponding site-specific functional poly(propylene carbonate)s (PPC),diversifying the topology of polymers.Furthermore,porphyrin-capped PPCs with controllable Mn in the range of 1,000-16,800 g mol-1 were obtained by using monofunctional CTC (CTCOH).Moreover,different from traditional "catalyst+CTA" systems,a novel dynamic network transfer mechanism of CTCOH was proposed.This study provides a CTC strategy for the synthesis of site-specific functional polymers.