Spectral change and far-red emission of Mn2+ ions co-doped NaSrB5O9∶Dy3+ luminescence material for plant growth LEDs

• 作者: K.Munirathnam Koduru Mallikarjuna R.Vijaya P.C.Nagajyothi K.Ramakrishna Reddy M.Srinivas
• 来源期刊: 稀土学报（英文版）
• 年，卷（期）: 2022,（2）
• 所属期刊栏目: SPECTROSCOPY, LUMINESCENCE AND PHOSPHORS
• 页码范围: 218-225
• 页数: 8页
• 语种: 英文

摘要

Due to the characteristic emission of phosphors,phosphor-converted LEDs have been employed to provide the requisite light sources for indoor plant growth in the optical agricultural industry.Herein,we prepared a series of Mn2+ co-doped NaSrB5O9∶Dy3+ phosphors via a solid-state reaction method.These phosphors have significant three-band emissions at 467 nm (blue region),606 nm (orange region),and 765 nm (far-red region),ascribed to the 4F9/2-6H15/2 and 4F9/2-6H13/2 transitions of the Dy3+ ions and the 4T1g(G)-6A1g(S) spin-forbidden transition of the Mn2+ ions,respectively,when excited by light of 376 nm(near-UV region).The co-dopant in the host material facilitates tunable photoluminescence (PL) due to energy transfer from the Dy3+ ions to the Mn2+ ions.The three emission peaks from the prepared phosphors well match with the absorption spectra of the photosynthesis pigments of plants,chlorophyll and phytochrome,which can absorb blue (400-500 nm),orange-red (550-700 nm),and infrared (IR)radiation,indicating that these phosphors have potential applications in the fabrication of plant-growth LEDs.Prior to the PL studies,the structure of the phosphors was determined by X-ray diffraction,refined by Rietveld method and chemically quantified by X-ray Photoelectron spectroscopy.