Self-Consistent Calculations on the Atomic Electron Affinity and Ionization Energy with Taking Effects of the Nonspherical Distribution of Electrons into Account

• 作者: Katsuhiko Higuchi Masahiko Higuchi Mitiyasu Miyasita
• 来源期刊: 现代物理(英文)
• 学科: 化学
• 关键词: Nonspherical Distribution of ELECTRONS Spherical Approximation ATOMIC Structure First-Row ATOMS Electron AFFINITY IONIZATION Energy
• 年，卷（期）: 2011,（10）
• 页码范围: 1161-1165
• 页数: 5页
• 分类号: O6

摘要

We perform the self-consistent calculations on the atomic electron affinity and ionization energy for the first-row atoms by means of our scheme. A striking feature of the present work is the variational method with taking into account effects of the nonspherical distribution of electrons explicitly. Comparing the present results with those of the conventional spherical approximation, the systematical improvement can be found. This means that effects of the nonspherical distribution of electrons may play an essential role on the description of the atomic structures.