Solid state transformation of <i>cis</i>and <i>trans</i>methylcyclopentadienyl molybdenumdicarbonyltriphenylphosphineiodide on pelleting utilizing different diluents

• 作者: Olalere G. Adeyemi Umaru Salami
• 来源期刊: 无机化学期刊(英文)
• 学科: 化学
• 关键词: Solid State cis/trans-[(η5-C5H4Me)Mo(CO)2PPh3I] PELLETING DILUENTS FT IR
• 年，卷（期）: 2012,（2）
• 页码范围: 28-32
• 页数: 5页
• 分类号: O6

摘要

[(η5-C5H4Me)Mo(CO)2PPh3I] undergoes solid state transformation on the formation of a good pellet for FT IR measurement. There was a formation of the products mixture on pelleting using different diluents of group I metal salts on either the cis or the trans isomer of the [(η5-C5H4Me)Mo(CO)2PPh3I] complex. The cis or the trans isomer gave the same IR spectra i.e. a mixture of cis and trans isomer of the complex. It does not matter the isomer started with in the course of solid state transformation reaction, an equilibrium ratio of 30/70 (trans/cis) will still be achieved. The solid state IR spectra show very strong peaks at νco 1957, 1947 and strong peaks at 1867, 1853 cm–1. The individual IR cis/trans isomer will therefore show at 1947 and 1853/1957 and 1867 cm–1. The solution IR spectra gave, cis = 1961, 1875 and trans = 1963, 1882 cm–1 in dry CHCl3. Hence, most of the solid state IR measurement of the organometallic complex of the type (η5-C5H4Me)Mo(CO)2(PPh3)I on pelleting will give isomer mixture.